| SBA-15/NiCl2催化超声合成喹喔啉衍生物 |
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| 引用本文： | 李琳琳,刘心韵,付海,龚维,陈卓,尹晓刚. SBA-15/NiCl2催化超声合成喹喔啉衍生物[J]. 合成化学, 2020, 28(4): 336-340. DOI: 10.15952/j.cnki.cjsc.1005-1511.19003 |
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| 作者姓名： | 李琳琳 刘心韵 付海 龚维 陈卓 尹晓刚 |
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| 作者单位： | 1. 贵州师范大学 化学与材料科学学院 贵州省功能材料化学重点实验室，贵州 贵阳 550001；2. 贵州医科大学 药学院，贵州 贵阳 550025 |
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| 摘 要： | 以苯偶姻和邻苯二胺为原料,SBA/NiCl2为催化剂,在超声条件下合成了喹喔啉衍生物,其结构经1H NMR和IR确证。考察催化剂类型、原料摩尔比和催化剂的用量对产率的影响。在最佳条件(苯偶姻和邻苯二胺物质的量比为1.0/1.0,催化剂用量为苯偶姻的10 mmol%,于70℃超声反应5 min)下,产率可达94.7%。
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| 关 键 词： | 苯偶姻 邻苯二胺 介孔分子筛 喹喔啉 超声合成 |
| 收稿时间： | 2018-12-08 |
Ultrasonic Synthesis of Quinoxaline Derivatives Catalyzed by SBA-15/NiCl2 |
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| LI Lin-lin,LIU Xin-yun,FU Hai,GONG Wei,CHEN Zhuo,YIN Xiao-gang. Ultrasonic Synthesis of Quinoxaline Derivatives Catalyzed by SBA-15/NiCl2[J]. Chinese Journal of Synthetic Chemistry, 2020, 28(4): 336-340. DOI: 10.15952/j.cnki.cjsc.1005-1511.19003 |
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| Authors: | LI Lin-lin LIU Xin-yun FU Hai GONG Wei CHEN Zhuo YIN Xiao-gang |
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| Affiliation: | 1. Guizhou Key Laboratory of Functional Materials Chemistry, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China；
2. School of Pharmaceutical Sciences, Guizhou Medical University, Guiyang 550025, China |
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| Abstract: | Several quinoxaline derivatives were synthesized under ultrasonic conditions using benzoin and o-phenylenediamine as raw materials and SBA/NiCl2 as catalyst.The structures were confirmed by 1H NMR and IR.The effects of catalyst type,molar ratio of raw materials and amount of catalyst on the yield were investigated.The optimal conditions were as follows:the molar ratio of benzoin and o-phenylenediamine was 1.0/1.0,the amount of catalyst was 10 mmol%,and the ultrasound was applied at 70℃for 5 min.The yield was 94.7%. |
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| Keywords: | benzoin o-phenylenediamine mesoporous molecular sieve quinoxaline ultrasonic synthesis |
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