Schwingungsspektroskopische Untersuchungen an den Organohydrogensilanen (XCH2)(CH3)2SiH (X = Cl,Br, J), X(YO)2SiH (X = CH3, C2H5/Y = CH3, C2H5 … tert.-C4H9), (C6H5)2SiH2 und C6H5SiH3 |
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Authors: | P Reich |
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Abstract: | Infrared and Raman Spectroscopic Investigations on the Organosubstituted Silicon Hydrides (XCH2)(CH3)2SiH (X = Cl, Br, J), X(YO)2SiH (X = CH2, C2H5/Y = CH3, C2H5 … tert.-C4H9), (C6H5)2SiH2 and C6H5SiH3 Typical band splittings, specially for the SiH stretching vibration, are shown in the infrared and Raman spectra of the silicon hydrides (XCH2)(CH3)2SiH (X = Cl, Br, J), and X(YO)2SiH (X = CH3, C2H5/Y = CH3, C2H5 … tert.-C4H9). The cause of this behavior is in all probability the existence of rotational isomers. Raman polarization measurements at organosubstituted silicon di- and trihydrides demonstrate the accidental degeneracy of the SiH valence vibrations. |
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