195Pt-NMR. Spectroscopy. The direct measurement of the values 1J (195Pt, 14N) and chemical shift data for the complexes trans-[PtCl2(C2H4) (substituted pyridine)] |
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Authors: | Herbert Motschi Siu N Sze Paul S Pregosin |
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Abstract: | The values nJ (195Pt, 14N) are shown to be measurable directly from the 195Pt spectrum for a variety of complexes containing nitrogen ligands. The sample temperature can play an important role in determining the width of the 195Pt signal. 195Pt chemical shifts for the complexes trans-PtCl2(C2H4) (substituted pyridine)] have been measured. Methyl substitution at the 2- and 6-positions produces a relatively large downfield shift. |
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