Nb2O5-carbon core-shell nanocomposite as anode material for lithium ion battery |
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Authors: | Ge Li Xiaolei Wang Xueming Ma |
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Affiliation: | 1. Department of Physics, East China Normal University, Shanghai 200241, China;2. Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, CA 90095, United States |
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Abstract: | Nb2O5-carbon nanocomposite is synthesized through a facile one-step hydrothermal reaction from sucrose as the carbon source, and studied as an anode material for high-performance lithium ion battery. The structural characterizations reveal that the nanocomposite possesses a core-shell structure with a thin layer of carbon shell homogeneously coated on the Nb2O5 nanocrystals. Such a unique structure enables the composite electrode with a long cycle life by preventing the Nb2O5 from volume change and pulverization during the charge-discharge process. In addition, the carbon shell efficiently improves the rate capability. Even at a current density of 500 mA·g?1, the composite electrode still exhibits a specific capacity of ~100 mAh·g?1. These results suggest the possibility to utilize the Nb2O5-carbon core-shell composite as a high performance anode material in the practical application of lithium ion battery. |
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Keywords: | niobium pentoxide core-shell long cycle life high performance anode lithium ion battery |
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