| The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol |
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| 引用本文： | Xue Song WU, Hong Sui SUN, Yi PAN, Hua Bing CHEN, Xiang Zhen SUN(Department of Chemistry,Nanjing University,Nanjing 210093). The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol[J]. 中国化学快报, 1999, 0(10) |
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| 作者姓名： | Xue Song WU Hong Sui SUN Yi PAN Hua Bing CHEN Xiang Zhen SUN(Department of Chemistry Nanjing University Nanjing 210093) |
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| 作者单位： | Department of Chemistry，Nanjing University，Nanjing 210093 |
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| 摘 要： | IntroductionThechemistryoforganoaluminum,organogalliumandorganoindiumcomplexeshasattractedmuchat'tentionduenotonlytotheirinterestingstructuralandchemicalpropertiesbutalsotheirapplicationinsemiconductormaterialsl-5.InthecourseofourstudiesonexploringvolatileMOCVDprecursorsthathavethepropertiesoflowertoxicityandhigherstability,wehaverecentlyreportedonthesynthesisandcharacterizationofintermolecularadducts'-',novelbondingmodecomplexes",',andthecomplexesinwhichN/Omixed-donorcrownethersasligands'l'…
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The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol |
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| Xue Song WU, Hong Sui SUN, Yi PAN, Hua Bing CHEN, Xiang Zhen SUN. The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol[J]. Chinese Chemical Letters, 1999, 0(10) |
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| Authors: | Xue Song WU Hong Sui SUN Yi PAN Hua Bing CHEN Xiang Zhen SUN |
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| Abstract: | The reaction of the trialkyl metals (R,M, R = Me, Et, M = Ga, In) withbenzo[h]quinolin-10-ol (HO-BQ) in a 1:1 molar ratio gave intramolecular N coordinatedcomplexes R2M-O-BQ (M = Ga, R = Me 1, Et 2) and (R2In-O-BQ)2 (M = In, R = Et 3, ) in 80-90%yield. The molecular structures of complexes 1 and 3 have been established by X-raycrystallography. |
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| Keywords: | Metal trialkyls gallium indium MOCVD precursors X-ray crystal structure. |
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