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Asymmetric synthesis of 6-formyl-1-alkoxycarbonylbicyclo[3.1.0]hex-2-ene-2-carboxylic acids by a novel buffer-mediated rearrangement |
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| Affiliation: | 1. Institut de Chimie Moléculaire de l''Université de Bourgogne (ICMUB), UMR 6302, CNRS, Université de Bourgogne Franche-Comté, 9 avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France;2. Laboratoire de Spectrochimie Infrarouge et Raman (LASIR), UMR 8516, CNRS, Université de Lille – Sciences et Technologies, 59655 Villeneuve d''Ascq Cedex, France |
| Abstract: | Asymmetric synthesis of 6-formyl-1-alkoxycarbonylbicyclo[3.1.0]hex-2-ene-2-carboxylic acids has been achieved and the absolute configurations of the products of a novel buffer-mediated rearrangement have been established. |
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