Preparation of chiral 1,3 skipped anti- and syn-tetrols via highly enantioselective biocatalytic resolution |
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| Affiliation: | Dipartimento di Chimica, Università della Basilicata, Via N. Sauro 85, 85100 Potenza, Italy;Laboratoire de Chimie Organique, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05, France;Department of Chemistry, Fukushima Medical University, Hikariga-oka, Fukushima 960-1295, Japan;Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India;Dipartimento di Chimica, Università Ca’ Foscari di Venezia, Dorsoduro 2137, I-30123 Venezia, Italy;Division of Organic Chemistry: Technology, National Chemical Laboratory, Pune 411 008, India;Institute of Bioengineering College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China |
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| Abstract: | Biocatalytic resolution of the 7-benzyloxy-3,5-anti-dioxolan-1,3,5,7-tetrol and the 7-benzyloxy-3,5-syn-dioxolan-1,3,5,7-tetrol was found to be highly enantioselective leading to differently functionalized chiral tetrols with significantly high e.e. |
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