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Catalytic enantioselective oxidation of sulfides to sulfoxides with a renewable hydroperoxide |
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| Affiliation: | 1. Hubei Collaborative Innovation Center of Targeted Antitumor Drug, Jingchu University of Technology, Jingmen 448000, PR China;2. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062, PR China;3. Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, PR China |
| Abstract: | The catalytic asymmetric oxidation of prochiral sulfides can be conveniently performed by using an easily accessible and renewable furyl hydroperoxide in the presence of the chiral Ti(O-i-Pr)4/BINOL/H2O system. |
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