Poly(epichlorohydrin) modified with 3,4,5‐tris(dodecyloxy)benzoate: The structure and dynamics of the aliphatic side chains in the columnar mesophase |
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Authors: | Marta Giamberini,Joan Carles Ronda,Jos Antonio Reina |
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Affiliation: | Marta Giamberini,Joan Carles Ronda,José Antonio Reina |
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Abstract: | We investigated the dynamics and structure of the aliphatic side chains of a randomly grafted copolymer, obtained through the chemical modification of poly(epichlorohydrin) with potassium 3,4,5‐tris(dodecyloxy)benzoate, with solid‐state 13C NMR. Below 283 K, the aliphatic chains partially crystallized in an all‐anti conformation. The calorimetric data were compatible with an orthorhombic packing. Below 323 K, the polymer exhibited a columnar mesophase. Spin–lattice relaxation times were determined in this temperature range and at 333 K, that is, in the isotropic phase. In the liquid‐crystalline state, some carbons exhibited a double decay in the spin–lattice relaxation, and this was attributed to presence of the liquid‐crystalline phase. This hypothesis was supported by a conformational analysis performed by molecular modeling. The activation energies of the relaxation processes in the mesophase were also estimated. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2099–2111, 2005 |
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Keywords: | crystallization differential scanning calorimetry (DSC) liquid‐crystalline polymers (LCP) NMR supramolecular structures WAXS |
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