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Kinetically controlled phase transitions in liquid‐crystalline polymers. II. Isothermal degradation of ferroelectric switching in a chiral side‐chain polysiloxane during slow smectic B phase formation
Authors:Mikhail Kozlovsky  Kent Skarp
Abstract:The kinetics of phase transformations in a chiral siloxane polymer has been studied with an Avrami analysis of the differential scanning calorimetry data. Ferroelectric switching has been measured as a function of the driving voltage and temperature. The evolution of the switching at a constant temperature has been studied within the temperature range of the kinetically governed smectic C*/smectic B phase transition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 1779–1784, 2005
Keywords:ferroelectric liquid crystals  kinetics (polym  )  optical switching  phase transitions  side‐chain polymers
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