| Abstract: | The basic characteristics of fluorosulfation of fluoroalkylhalides (effect of the structure of the polyfluoroalkyl, nature of the halogen, acid catalysis, etc.) with halogen fluorosulfates and peroxydisulfuryl difluoride were investigated. A mechanism was proposed for formation of fluorosulfonic acid fluoroalkyl esters based on the experimental and quantum chemical data.A. N. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1718–1732, August, 1992. |
