Catalytic deoxygenation of pyridine N-oxides with N-fused porphyrin rhenium complexes |
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| Authors: | Motoki Toganoh |
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| Affiliation: | Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan |
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| Abstract: | Deoxygenation reactions of pyridine N-oxide derivatives catalyzed by N-fused porphyrin rhenium(VII) trioxo complexes are developed, affording the corresponding pyridine derivatives in quantitative yields with excellent turnover numbers up to 340,000. |
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