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Efficient ligand-free nickel-catalyzed C-S cross-coupling of thiols with aryl iodides
Authors:Suribabu Jammi
Institution:Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781 039, India
Abstract:NiCl2·6H2O efficiently catalyzes the C-S bond formation by the cross-coupling of aryl iodides with thiols in tetrabutylammonium bromide (TBAB) in excellent yield. The reaction functions in air and the NiLn-TBAB can be recovered and recycled without the loss of activity.
Keywords:C-S bond formation  Cross-coupling  Thiols  Aryl iodides  Synthetic method
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