| SYNTHESIS AND SPECTRAL STUDIES OF(μ-PHENYLTHIO) (μ-ALKYLTHIO) HEXACARBONYLDIIRON COMPLEXES |
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| 摘 要： | Through reductive reaction between PhL1 and μ-S2 Fe (CO/6,tollowed by nucleophilicsubstitution of the intermediate (μ-PhS} (μ-LIS} Fe2 (CO)6 toward RX,nine Fe-S clus-ter complexes of (μ-PhS)(μ-RS)Fe2(CO)6 series have been synthesized.The influence of RX structures on the activities in nucleophilic substitution has been examined and possible steroisomers and isomer ratios of the complexes determined.In addition,the regular variations of isomer's CH3-S and CH2-S which are caused by the anisotropic effects of C-O and orientations of unshared electron pairs on sulfurs,have also been preliminarily discussed.
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| 收稿时间： | 1985-02-08 |
SYNTHESIS AND SPECTRAL STUDIES OF(μ-PHENYLTHIO) (μ-ALKYLTHIO) HEXACARBONYLDIIRON COMPLEXES |
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| Song Licheng,Hu Qingmei,Liu Xiangyang,Wang Jicao. SYNTHESIS AND SPECTRAL STUDIES OF(μ-PHENYLTHIO) (μ-ALKYLTHIO) HEXACARBONYLDIIRON COMPLEXES[J]. Chemical Research in Chinese University, 1985, 1(2): 55-62 |
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| Authors: | Song Licheng Hu Qingmei Liu Xiangyang Wang Jicao |
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| Affiliation: | Department of Chemistry, Nankai University |
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| Abstract: | Through reductive reaction between PhL1and μ-S2Fe(CO)6,tollowed by nucleophilicsubstitution of the intermediate (μ-PhS)(μ-LaS)Fe2(CO)6toward RX,nine Fe-S Clus-ter Complexes of (μ-PhS)(μ-LaS)Fe2(CO)6series have been synthesized. The influence of RX structures on the activities in nucleophilic substitution has been examined and possible steroisomers and isomer ratios of the complexes determined. |
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