Role of radiolytically formed protonating agents in gas phase competitive reactions |
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| Authors: | G. Perez |
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| Affiliation: | (1) Instituto di Cromatografia del CNR, 00016 Monterotondo Stazione, C.P. 10, (Roma), Italy |
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| Abstract: | Radiolytically formed O2H+, N2H+, and CO2H+ ions were allowed to react with gaseous p-cymene. Dealkylation and isomerization reactions were observed with O2H+ and N2H+ ions, while only the first process occurred when CO2H+ ions were employed. The results show that dealkylation is favored with respect to isomerization as the protonation exothermicity decreases. |
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