Synthesis and Some Transformations of Complex Salts of Bis-o-dicarbollyliron(II), -cobalt(II), and -nickel(II)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis and Some Transformations of Complex Salts of Bis-o-dicarbollyliron(II), -cobalt(II), and -nickel(II)

Authors:	Zubreichuk Z. P. Erdman A. A. Ivko A. A. Maier N. A.

Affiliation:	(1) Institute of Physical Organic Chemistry, Academy of Sciences of Belarus, Minsk, Belarus;(2) Institute of New Material Chemistry, Academy of Sciences of Belarus, Minsk, Belarus

Abstract:	The complex salts [(o-C2B9H11)2M³⁺]₂M'²⁺·4bipy, where M = Fe, Co, or Ni, M' = Fe, Co, Ni, Cu, Mn (M M'), and bipy is 2,2'-bipyridyl, were synthesized. The salts with M = Ni decompose to give 3-(2,2'-bipyridyl)-3,1,2-nickelacarborane, when refluxed in alcohol, and to give 2-(2,2'-bipyridyl)-2,1,7-nickel acarborane, when refluxed in dodecane (216°C).

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