Desymmetrization of 1,4-cyclohexadienyltriisopropoxysilane using copper catalysis |
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| Authors: | Umeda Rui Studer Armido |
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| Affiliation: | Organisch-Chemisches Institut, Westf?lische Wilhelms-Universit?t, Corrensstrasse 40, 48149 Münster, Germany. |
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| Abstract: | The first catalytic desymmetrization in the field of allylsilane chemistry is presented. Desymmetrization of cyclohexadienyltriisopropoxysilane is achieved using coppper catalysis. High diastereo- and enantioselectivities are obtained, and the product dienes are highly valuable building blocks for natural product synthesis. |
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