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Co3O4纳米片的制备及其电化学电容性能
引用本文:张 防,郝 亮,傅清宾,张校刚.Co3O4纳米片的制备及其电化学电容性能[J].无机化学学报,2010,26(5):827-831.
作者姓名:张 防  郝 亮  傅清宾  张校刚
作者单位:南京航空航天大学材料科学与技术学院,南京,210016
摘    要:以配位超分子化合物为前驱物,通过液相氧化分解得到了六方形CoOOH纳米片,进而在空气中热处理制得了Co3O4纳米片。利用XRD、TEM、FESEM对CoOOH和Co3O4纳米片的结构和形貌进行了表征。电化学测试表明,Co3O4纳米片电极在6 mol·L-1 KOH溶液中表现出良好的电化学电容特性,在电流密度为1 A·g-1其单电极比容量可达到227 F·g-1

关 键 词:Co3O4    纳米片    电容性能

Preparation and Electrochemical Capacitance Performance of Co3O4 Nanosheets
ZHANG Fang,HAO Liang,FU Qing-Bin and ZHANG Xiao-Gang.Preparation and Electrochemical Capacitance Performance of Co3O4 Nanosheets[J].Chinese Journal of Inorganic Chemistry,2010,26(5):827-831.
Authors:ZHANG Fang  HAO Liang  FU Qing-Bin and ZHANG Xiao-Gang
Institution:College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 and College of Material Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016
Abstract:Co3O4 nanosheets with hexagonal shape were prepared through a facile complex-precursor solutions procedure and sequential thermal decomposition at atmospheric pressure. The structure and morphology of products were characterized by XRD, TEM and FESEM. The electrochemical performance of Co3O4 electrode was investigated by cyclic voltammetry (CV) and galvanostatic charge/discharge measurements. The electrochemical experiment revealed that Co3O4 electrode exhibited good electrochemical capacitance performance in 6 mol·L-1 KOH electrolyte. Its specific capacitance as single electrode is up to 227 F·g-1 at 1 A·g-1.
Keywords:Co3O4  nanosheets  capacitor performance
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