Assembly of CdI2-type coordination networks from triangular ligand and octahedral metal center: topological analysis and potential framework porosity |
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Authors: | Zheng Sheng-Run Yang Qing-Yuan Liu Yong-Ru Zhang Jian-Yong Tong Ye-Xiang Zhao Cun-Yuan Su Cheng-Yong |
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Affiliation: | MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China. |
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Abstract: | Reaction of a rigid triangular ligand 2,4,6-tris[4-(1H-imidazole-1-yl)phenyl]-1,3,5-triazine (TIPT) with Cd2+ ions affordedrare non-interpenetrating CdI2-type networks which display high thermostability and potential porosity; the topological character of the CdI2-type networks have been analyzed in comparison with three common uniform (4,4), (6,3) and (3,6) plane nets. |
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