| 无溶剂条件下锰 (Ⅲ)-席夫碱配合物催化过氧化氢氧化醇 |
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| 引用本文： | Hamid GOLCHOUBIAN,Seyyed Ebrahim BABAEI. 无溶剂条件下锰 (Ⅲ)-席夫碱配合物催化过氧化氢氧化醇[J]. 催化学报, 2010, 31(6): 615-618. DOI: 10.1016/S1872-2067(09)60074-7 |
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| 作者姓名： | Hamid GOLCHOUBIAN Seyyed Ebrahim BABAEI |
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| 作者单位： | Hamid GOLCHOUBIAN(Department of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran);Seyyed Ebrahim BABAEI(Departmant of Chemistry, Islamic Azad University-Ghaemshahr Branch, Ghaemshahr, Iran) |
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| 基金项目： | Supported by the Islamic Azad University-Ghaemshahr branch of the Islamic Republic of Iran |
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| 摘 要： | Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(III) Schiff-base complex as a catalyst under solvent-free conditions. The oxidation of alcohols occurred at 50 °C to give the corresponding ketones or carboxylic acids with a yield higher than 60%.
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| 关 键 词： | alcohol oxidation hydrogen peroxide Schiff-base complex Mn(III) complex ketone |
| 收稿时间： | 2010-06-25 |
Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant |
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| Hamid GOLCHOUBIAN,Seyyed Ebrahim BABAEI. Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant[J]. Chinese Journal of Catalysis, 2010, 31(6): 615-618. DOI: 10.1016/S1872-2067(09)60074-7 |
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| Authors: | Hamid GOLCHOUBIAN Seyyed Ebrahim BABAEI |
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| Affiliation: | 1. Department of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran
2. Departmant of Chemistry, Islamic Azad University-Ghaemshahr Branch, Ghaemshahr, Iran |
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| Abstract: | Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylie acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(Ⅲ)Schiff-base complex as a catalyst under solvent-flee conditions. The oxidation of alcohols occurred at 50 ℃ to give the corresponding ketones or carboxylic acids with a yield higher than 60%. |
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| Keywords: | alcohol oxidation hydrogen peroxide Schiff-base complex ketone |
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