New method for preparation of α-substituted acrylonitrile derivatives |
| |
| Authors: | N P Tsvetkov V E Vakhmistrov A B Koldobsky V N Kalinin |
| |
| Institution: | (1) The Higher Chemical College, Russian Academy of Sciences, 9 Miusskaya pl., 125047 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| |
| Abstract: | The method for the preparation of α-substituted acrylonitrile derivatives by the quaternization of the nitrogen atom of both
Me2N groups in the corresponding substituted 3-(dimethylamino)propanal dimethylhydrazones followed by the Hoffman decomposition
of the resulting diiodides was developed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1707–1709, September, 1999. |
| |
| Keywords: | transmetallation quaternization Hoffman decomposition acrylonitriles hydrazonium salts dimethylhydrazones |
| 本文献已被 SpringerLink 等数据库收录！ |
|
