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New versatile building block for the construction of tetrathiafulvalene-based donor-acceptor systems |
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| Authors: | Baffreau Jérôme Dumur Frédéric Hudhomme Piétrick |
| Affiliation: | Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers (CIMMA), Groupe Synthèse Organique et Matériaux Fonctionnels (SOMaF), UMR CNRS 6200, Université d'Angers, 2 Bd Lavoisier, F-49045 Angers, France. |
| Abstract: | [reaction: see text] A new dissymmetrical tetrathiafulvalene (TTF) derivative 1 was synthesized as a versatile building block to reach TTF-based donor-acceptor assemblies incorporating C(60) in triad C(60)-TTF-C(60) 2 and/or p-benzoquinone (Q) in fused dyad Q-TTF 3 and triad Q-TTF-C(60) 4. |
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