Nickel(0) triethyl phosphite complex-catalyzed allylic substitution with retention of regio- and stereochemistry |
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| Authors: | Yatsumonji Yasutaka Ishida Yusuke Tsubouchi Akira Takeda Takeshi |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan. |
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| Abstract: | Nickel(0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio- and stereochemistry. |
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