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Electronic structure and reactivity of S—S dications |
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| Authors: | Pissarev S A Shevchenko N E Nenaidenko V G Balenkova E S |
| Institution: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992 Moscow, Russian Federation |
| Abstract: | The electronic structure and reactivity of some S—S dications were studied at the MP2/6-31G* level of theory. The results obtained indicate a stepwise electrophilic addition of disulfonium dication moiety to the double C=C bond to be the preferable mechanism. |
| Keywords: | disulfonium dications ab initio quantum-chemical calculations electrophilic addition conformational analysis |
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