ESR study of the reaction of substituted nitrosobenzenes with aliphatic and saturated alkylaromatic hydrocarbons |
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| Authors: | P. Simon, L. Sü megi, A. Rockenbauer, I. Nemes F. Tü ds |
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| Affiliation: | (1) Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P. O. Box 17, H-1525 Budapest, Hungary |
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| Abstract: | We have found that nitrosobenzenes spontaneously react with saturated hydrocarbons in the absence of oxygen and light. For interpretation of this general phenomenon a new reaction pathway has been assumed. In light of these results special care should be taken when applying nitrosobenzenes for inhibition and spin trapping as well as organic synthesis in saturated organic solvents, which are supposed to be inert.
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