Synthesis and properties of azidostyrylquinolines |
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Authors: | M F Budyka N V Biktimirova T N Gavrishova |
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Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432 Moscow Region |
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Abstract: | Isomeric azidostyrylquinolines with a 4-azidostyryl group in position 2 or 4 of the quinoline ring have been synthesized.
In the neutral form the azidostyrylquinolines absorb in the near UV but the protonated species absorb in the short wavelength
region of the visible spectrum. In both forms the azides are lightsensitive and decompose under the influence of light with
a quantum yield close to 1.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 555–561, April, 2007. |
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Keywords: | aromatic azide styrylquinoline light sensitivity absorption spectrum hotoaffinity probe photodissociation |
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