Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand |
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Authors: | J G Ma?ecki A Maroń |
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Institution: | 1. Department of Crystallography, Institute of Chemistry, University of Silesia, ul. Szkolna 9, 40-006, Katowice, Poland
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Abstract: | Chloride and pseudohalide (N3 ?, NCS?) hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand were synthesized and characterized by IR, 1H, and 31P NMR, electronic absorption and emission spectroscopy and X-ray crystallography. The electronic structures of the complexes were calculated by density functional theory (DFT) on their crystal structures. The spin-allowed singlet–singlet electronic transitions of the complexes were calculated by time-dependent DFT, and the UV–Vis spectra have been discussed on these basis. The emission properties of the complexes were also studied. |
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