N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions: synthesis, crystal structures and application in the coupling of terminal alkynes with arylboronic acids |
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Authors: | Hong-Mei Li Chen Xu Lu-Meng Duan Xin-Hua Lou Zhi-Qiang Wang Zhen Li Yao-Ting Fan |
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Affiliation: | 1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, China 2. Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, Henan, China
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Abstract: | Two air-stable N-heterocyclic carbene (NHC) adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions 2–3 have been easily prepared from the bridge-splitting reaction of the palladacyclic dimer 1 and anion exchange reaction, respectively. They were characterized by elemental analysis, IR, 1H, and 13C NMR. Additionally, the structures of these complexes were determined by single-crystal X-ray analysis. These adducts have been successfully applied to the coupling of terminal alkynes with arylboronic acids under atmospheric conditions. |
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