Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature |
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| Authors: | Takeshi NishiiTomomi Ouchi Aya MatsudaYuka Matsubara Yuuko HaraguchiTomomi Kawano Hiroto KakuMitsuyo Horikawa Tetsuto Tsunoda |
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| Affiliation: | Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima 770-8514, Japan |
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| Abstract: | A modified version of Markó’s aerobic oxidation procedure, using highly pure (99.995+%) CuCl with 4,7-diphenyl-1,10-phenanthroline (dpPhen), DBAD, and Cs2CO3 (98% purity) successfully oxidized primary and secondary alcohols to the corresponding aldehydes and ketones in excellent yield at room temperature with either air or molecular oxygen under atmospheric pressure. |
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| Keywords: | Aerobic oxidation 4,7-Diphenyl-1,10-phenanthroline Copper catalyst |
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