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Single chemosensor for multiple analytes: chromogenic and fluorogenic detection for fluoride anions and copper ions
Authors:Hong Yang  Haisheng Song  Yachao Zhu  Shiping Yang
Affiliation:The Education Ministry Key Laboratory of Resource Chemistry & Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200233, PR China
Abstract:A o-hydroxybenzoyl-(N-butyl-4,6-naphthamimide) hydrazone (1) has been synthesized. Compound 1 displayed high selectivity for F? and Cu2+ with UV/vis absorption and fluorescence spectra, respectively. In the presence of F?, while the absorption peak of 1 showed the red shift, its fluorescent intensity decreased due to deprotonation interaction. In the presence of Cu2+, both the absorption and fluorescence peaks decreased because of the coordination interaction.
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