Synthesis and photochromic reactivity of a new class of photochromic diarylethene dimer-containing dithieno[3,2-b:2′3′-d]thiophene |
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Authors: | Hongke Wang Wei Xu Daoben Zhu |
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Institution: | 1. Beijing National Laboratory for Molecular Sciences, Organic Solid Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;2. Graduate School of Chinese Academy of Sciences, Beijing 100049, PR China |
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Abstract: | Novel photochromic diarylethene dimers containing dithieno3,2-b:2′3′-d]thiophene were synthesized and their photochromic properties were studied in solution as well as in the crystalline phase. Only the isomer with the diarylethene units one in open-form and one in closed-form was produced upon irradiation with ultraviolet light because of the intramolecular excitation energy transfer in this isomer. Their electrochemical properties were also investigated associating with computational studies. |
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