Cascade cyclization of aryldiynes using iodine: synthesis of iodo-substituted benzo[b]naphtho[2,1-d]thiophene derivatives for dye-sensitized solar cells |
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| Authors: | Giovanni Ferrara Tienan Jin Md Akhtaruzzaman Ashraful Islam Liyuan Han Hua Jiang Yoshinori Yamamoto |
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| Institution: | 1. WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;2. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan;3. Photovoltaic Materials Unit, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan;4. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China |
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| Abstract: | A facile, efficient, and general synthetic method for iodo-substituted benzob]naphtho2,1-d]thiophenes has been developed via a cascade cyclization of thioanisole-substituted aryldiynes using iodine. A new donor–π linker–acceptor (D–π–A) organic dye, G1, with the benzob]naphtho2,1-d]thiophene moiety as an electron donor has been synthesized, and the performance of dye-sensitized solar cell based on G1 has been investigated. |
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