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A benzimidazole-based fluorescent sensor for Cu2+ and its complex with a phosphate anion formed through a Cu2+ displacement approach
Authors:Preeti Saluja  Navneet Kaur  Narinder Singh  Doo Ok Jang
Institution:1. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001, India;2. Centre for Nanoscience & Nanotechnology, Panjab University, Chandigarh, Punjab 160014, India;3. Department of Chemistry, Yonsei University, Wonju 220-710, Republic of Korea
Abstract:A benzimidazole-based imine linked receptor was synthesized for fluorescent recognition of Cu2+ in a CH3CN/H2O (8:2, v/v) solvent system. The receptor offers an opportunity for the selective estimation of Cu2+ in the presence of another metal ion at equimolar concentration. The Cu2+ complex with the receptor acted as a sensor for a phosphate anion, and the phosphate recognition event restored the fluorescence intensity of the receptor.
Keywords:
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