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A palladium-catalyzed one-pot procedure for the regioselective dimerization and cyanation of indoles
Authors:Ebrahim Kianmehr  Mohammad Ghanbari  Nasser Faghih  Frank Rominger
Institution:1. School of Chemistry, College of Science, University of Tehran, Tehran 1417614411, Iran;2. Institute of Organic Chemistry, University of Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
Abstract:A one-pot method for the regioselective dimerization and cyanation of indoles has been developed. The reaction uses safe and nontoxic K4Fe(CN)6]·3H2O as the cyanating agent which introduces selectively a cyano group into the 3-position of biindoles with high efficiency.
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