Four component reaction of aldehydes,isocyanides, Me3SiN3, and aliphatic alcohols catalyzed by indium triflate |
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Authors: | Hikaru Yanai Takuji Sakiyama Tomoko Oguchi Takeo Taguchi |
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Affiliation: | School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan |
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Abstract: | In the presence of catalytic amount of indium(III) Lewis acids, the four component reaction of aldehydes, isocyanides, trimethylsilyl azide and aliphatic alcohols smoothly proceeded to give alkoxylated 1H-tetrazole products in good yields. In particular, In(OTf)3 and In(ONf)3 showed notably high level of catalytic activity in this reaction. |
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