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Rapid formation of diphenylmethyl ethers and thioethers using microwave irradiation and protic ionic liquids |
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| Authors: | Jarrad M. Altimari Joshua P. Delaney Linden Servinis Jennifer S. Squire Megan T. Thornton Simren K. Khosa Benjamin M. Long Mark D. Johnstone Cassandra L. Fleming Frederick M. Pfeffer Shane M. Hickey Matthew P. Wride Trent D. Ashton Bronwyn L. Fox Nolene Byrne Luke C. Henderson |
| Affiliation: | 1. Deakin University, Strategic Research Center for Biotechnology, Chemistry and Systems Biology, Pigdons Road, Waurn Ponds Campus, Waurn Ponds, Victoria 3216, Australia;2. Institute of Technology and Research Innovation, Deakin University, Pigdons Road, Waurn Ponds Campus, Waurn Ponds, Victoria 3216, Australia |
| Abstract: | Using microwave irradiation and protic ionic liquids (pIL) as co-solvent and catalyst for the synthesis of several diphenylmethyl ethers was achieved. The desired ethers were isolated simply by filtration through a silica plug to remove the pIL and proceeded in high yields (60–98%). These reactions were extremely rapid (10–30 min) and occurred under mild conditions (80 °C). This protocol was also successfully applied to the synthesis of thioethers. |
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