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Amine-directed intramolecular hydroacylation of alkenes and alkynes
Authors:Holly D. Bendorf  Kyle E. Ruhl  Andrew J. Shurer  Jennie B. Shaffer  Tess O. Duffin  Theresa L. LaBarte  Michelle L. Maddock  Oscar W. Wheeler
Affiliation:Department of Chemistry, Lycoming College, Williamsport, PA 17701, United States
Abstract:Medium-ring heterocycles are prepared via an amine-directed, rhodium(I)-catalyzed intramolecular hydroacylation. The presence of an allyl substituent on the amine accelerates the reaction and increases product yields.
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