Oxidation of alcohols by chlorine dioxide in organic solvents |
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| Authors: | E. S. Ganieva I. M. Ganiev S. A. Grabovskiy N. N. Kabalnova |
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| Affiliation: | 1.Institute of Organic Chemistry,Ufa Scientific Center of the Russian Academy of Sciences,Ufa,Russian Federation |
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| Abstract: | The kinetics of oxidation of a series of alcohols (propan-2-ol, 2-methylpropan-1-ol, butan-1-ol, butan-2-ol, 3-methylpentan-1-ol, heptan-4-ol, decan-2-ol, cyclohexanol, borneol) by chlorine dioxide in organic solvents was studied using spectrophotometry. The reaction is described by the second-order rate equation w = k[ROH][ClO2]. The rate constants were measured in the range of 10–60 °C, and the activation parameters of the processes were calculated. The products were identified, and the yields were determined. |
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