凝固浴温度对PVDF-g-PNIPAAm温度敏感膜成膜过程与性能的影响

通过自由基共聚的方法制备了聚偏氟乙烯-g-聚(N-异丙基丙烯酰胺)(PVDF-g-PNIPAAm)共聚物,采用浸没沉淀相转化法制备了PVDF-g-PNIPAAm共聚膜.采用超声时域反射法研究了不同凝固浴温度下PVDF-g-PNIPAAm的成膜动力学,并研究了凝固浴温度对膜结构与性能的影响.结果表明,在不同凝固浴温度下,...

Influence of Coagulant Temperature on the Membrane Formation Process and Properties of PVDF-g-PNIPAAm Temperature-sensitive Membranes

The copolymer of poly(vinylidene fluoride) grafting poly(N-isopropylacrylamide) (PVDF-g-PNIPAAm) was synthesized and its flat sheet membranes were prepared. The influence of coagulant temperature on membrane formation kinetics was studied by the ultrasonic time-domain reflectometry. Based on the membrane formation kinetics, the influence of coagulant temperature on the structure and performance of PVDF-g-PNIPAAm membrane was studied. The results showed that the coagulant temperature influenced the membrane formation process greatly. The liquid-liquid dimixing dominated the dimixing process at different coagulant temperature. The needed membrane formation time of PVDF-g-PNIPAAm prepared at 30℃ was the longest and that of the membrane prepared at 40℃ was the shortest. The crystal properties of the PVDF-g-PNIPAAm membrane are dominated by the corresponding PVDF structure. The higher the coagulant temperature, the lower the degree of crystallinity is. The NIPAAm content on the surface of PVDF-g-PNIPAAm membrane is much higher than that of the PVDF-g-PNIPAAm copolymer. The NIPAAm content on the surface of PVDF-g-PNIPAAm membrane prepared at 30℃ is the highest. All the membranes presents finger-like pores .The membranes prepared at 30℃ has the largest pores and the highest porosity. The water flux of membrane prepared at 25℃ showed obvious temperature sensitivity and increased intensively at about 30℃.