Two new copper azido polymorphs: structures, magnetic properties, and effects of "noninnocent" reagents in hydrothermal methods |
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| Authors: | Liu Fu-Chen Zeng Yong-Fei Zhao Jiong-Peng Hu Bo-Wen Sañudo E Carolina Ribas Joan Bu Xian-He |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin 300071, China. |
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| Abstract: | Two new 3D copper(II) azido isomers, [Cu(N3)(nic)]infinity (1 and 2) (nic = nicotinate), have been synthesized and characterized. To the best of our knowledge, 1 is the first metal azido complex showing rutile-type topology, while 2 is a chiral compound obtained by spontaneous resolution upon crystallization. |
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