High-performance organic semiconductors: asymmetric linear acenes containing sulphur |
| |
Authors: | Tang Ming L Okamoto Toshihiro Bao Zhenan |
| |
Institution: | Department of Chemistry, Stanford University, California 94305, USA. |
| |
Abstract: | Two new linear acenes with fused thiophene units have been synthesized. These acenes have conjugation lengths between anthracene and pentacene. Thin films of these linear molecules were characterized by ultraviolet spectroscopy, X-ray diffraction, atomic force microscopy (AFM), and field-effect transistor measurements. Submonolayer AFM studies show growth that greatly resembles pentacene, while thin-film growth is dendritic. Mobilites as high as 0.47 cm2 V-1 s-1 have been found for the tetraceno2,3-b]thiophene and are as high as 0.15 cm2 V-1 s-1 for anthra2,3-b]thiophene. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|