Electrochemical and EPR studies of the corannulene ruthenium(II) sandwich complex [(eta6-C6Me6)Ru(eta6-C20H10)](SbF6)(2) |
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| Authors: | Angelici Robert J Zhu Bolin Fedi Serena Laschi Franco Zanello Piero |
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| Institution: | Ames Laboratory and Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, USA. |
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| Abstract: | The dication (eta6-C6Me6)Ru(eta6-C20H10)]2+ in propylene carbonate solution exhibits a sequence of reduction processes that is either metal-centered Ru(II)/Ru(I)/Ru(0)] or ligand-centered. The marginally stable Ru(I) monocation (eta6-C6Me6)Ru(eta6-C20H10)]+ has been characterized by EPR spectroscopy. The electrochemistry of C20H10 and EPR features of its stable monoanion C20H10]- have also been revisited. |
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