Catalytic properties of phosphorus-containing rhenium complexes in the hydrogenation of hexene-1 |
| |
| Authors: | V M Belousov T A Palchevskaya O M Negomedzyanova and K V Kotegov |
| |
| Institution: | (1) Institute of Physical Chemistry, 252028 Kiev, USSR |
| |
| Abstract: | Rhenium (V, VI) complexes with organophosphorus ligands proved to be catalytically active in hexene-1 hydrogenation. The kinetics of this process catalyzed by ReOCl3(PPh3)2 has been examined. The organic ligand in the coordination sphere of rhenium complexes was found to affect selectivity to olefin bonds or nitro groups in the hydrogenation of hydrocarbons.
             (V, VI)             -1.     , ReOCl3 (PPh3)2.  ,  .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
