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Electronic spectrum and magnetic properties of the Ni(II) telluromolybdate
Authors:I.L. Botto  E.J. Baran  G. Minelli
Affiliation:Area de Química Inorgánica, Facultad de Ciencias Exactas de la Universidad Nacional de La Plata, Calle 47 esq.115, 1900-La Plata, Argentina;Centro di Studio su “Struttura ed Attivitá Catalitica di Sistema di Ossidi”; Istituto di Chimica Generale ed Inorganica, Universitá di Roma, Roma, Italy
Abstract:The room temperature electronic (reflectance) spectrum and the magnetic properties of NiTeMoO6 in the temperature range 100 – 300 K were investigated in order to obtain a wider insight into the structural properties of the MIITeMoO6-type telluromolybdates. The results show that Ni(II) is located in a distorted octahedral environment and that there are important orbital contributions to the magnetic moment. Some data for CdTeMoO6 and CoTeMoO6 are also reported.
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