Salting-out in intercalation compounds: Removing copper from Cu3Mo6S8 by intercalating lithium |
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| Authors: | W.R. McKinnon J.R. Dahn |
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| Affiliation: | Solid State Chemistry, Chemistry Division, National Research Council of Canada, Ottawa K1A 0R9 CANADA |
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| Abstract: | We study the removal of the copper in Cu3Mo6S8 by the intercalation of lithium. For 0<×<1, LixCu3Mo6S8 is a single phase compound. For x?1, the copper atoms are forced out of the Mo6S8 host. We present a lattice-gas model which shows how the intercalation of Li can force the Cu out of the host. |
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