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Li+ transport in Li0.40MoO3 studied by pulse NMR |
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| Authors: | A Hardwick PG Dickens RCT Slade |
| Institution: | 1. Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, England;2. Department of Chemistry, University of Exeter, Stocker Road, Exeter EX4 4QD, England |
| Abstract: | Pulsed 7Li NMR relaxation time measurements are reported for the intercalate Li0.40MoO3 in the temperature range 200K < T < 460K at 20 MHz. Temperature dependences of T1 and T2 indicate translation of Li+ with EA = 23 kJ mol-1. The data lead to an estimate for the Li+ self-diffusion coefficient at 300K of D1300K ? 4 x 10-12 cm2 sec-1. |
| Keywords: | Author for correspondence |
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