A mathematical characterization of the groups of substitution isomerism of the linear alkanes |
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Authors: | Valentin Vankov Iliev |
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Institution: | (2) National Institute of Chemistry, Ljubljana, Slovenia;(3) The Institute of Medical Research and Occupational Health, Zagreb, Croatia;(4) The Rugjer Bošković Institute, Zagreb, Croatia; |
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Abstract: | In this paper, a mathematical characterization of Lunn–Senior’s groups of univalent substitution isomerism of the linear alkanes,
under some natural assumptions that reflect their common properties, is given. For each linear alkane, the number of its monosubstitution
derivatives, its di-substitution derivatives, and its tri-substitution derivatives as linear, quadratic, and cubic polynomial
expressions, respectively, in their number, is obtained. In principle, the number of derivatives of a given linear alkane
with any particular composition can be established. The same explicit expressions for the case of k-substitution homogeneous derivatives of the linear alkanes are obtained by Balasubramanian (Theoret. Chim. Acta (Berl.) 51:37,
1979). |
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Keywords: | |
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