Five-membered 2,3-dioxo heterocycles: XLIX. Reaction of methyl 1-aryl-3-aroyl-4,5-dioxo-4,5-dihydro-1<Emphasis Type="Italic">H</Emphasis>-pyrrole-2-carboxylates with N-substituted 3-amino-5,5-dimethyl-2-cyclohexenones |
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Authors: | Yu N Bannikova A N Maslivets Z G Aliev |
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Institution: | (1) Perm State University, ul. Bukireva 15, Perm, 614990, Russia;(2) Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia |
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Abstract: | Methyl 1-aryl-3-aroyl-4,5-dioxo-4,5-dihydro-1H-pyrrole-2-carboxylates react with N-substituted 3-amino-5,5-dimethyl-2-cyclohexenones to give 4 -hydroxy-1 -aryl-3 -aroyl-6,6-dimethyl-1 , 2,3,4,5,5 ,6,7-octahydro-1H,2 H-indole-3-spiro-2 -pyrrole-2,4,5 -triones. The structure of the products was proved by the X-ray diffraction data for the 1-cyclohexyl derivative.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 12, 2004, pp. 1840–1845.Original Russian Text Copyright © 2004 by Bannikova, Maslivets, Aliev.For communication XLVIII, see 1]. |
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