| Synthesis of Two Novel Rhenium（I） Bipyridyl Photosensitive Dyes |
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| 引用本文： | ShiGuoSUN XiaoJunPENG MingWenFAN YongQianXU LeiSHI LiChengSU. Synthesis of Two Novel Rhenium（I） Bipyridyl Photosensitive Dyes[J]. 中国化学快报, 2004, 15(8): 965-968 |
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| 作者姓名： | ShiGuoSUN XiaoJunPENG MingWenFAN YongQianXU LeiSHI LiChengSU |
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| 作者单位： | StateKeyLaboratoryofFineChemicals,DalianUniversityofTechnology,Dalian116012 |
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| 摘 要： | Two novel rhenium(I) 2, 2′-bipyridyl complexes, [(4,4′-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4′-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4′-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.
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| 关 键 词： | 合成 铼配合物 2，2′-二吡啶 光敏染料 红移 |
Synthesis of Two Novel Rhenium(I) Bipyridyl Photosensitive Dyes |
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| Shi Guo SUN,Xiao Jun PENG,Ming Wen FAN,Yong Qian XU,Lei SHI,Li Cheng SUNState Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian. Synthesis of Two Novel Rhenium(I) Bipyridyl Photosensitive Dyes[J]. Chinese Chemical Letters, 2004, 15(8): 965-968 |
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| Authors: | Shi Guo SUN Xiao Jun PENG Ming Wen FAN Yong Qian XU Lei SHI Li Cheng SUNState Key Laboratory of Fine Chemicals Dalian University of Technology Dalian |
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| Affiliation: | Shi Guo SUN,Xiao Jun PENG,Ming Wen FAN,Yong Qian XU,Lei SHI,Li Cheng SUNState Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012 |
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| Abstract: | Two novel rhenium(I) 2, 2'-bipyridyl complexes, [(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4'-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4'-di- COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized. Their ground stat?electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN. |
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| Keywords: | Rhenium(I) 2 2'-bipyridyl complex photosensitizer red shift. |
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