| 水溶液中一步合成二吡咯甲烷类化合物 |
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| 引用本文： | 吴振豪,胡江磊,王凯凯,高超,王洪宇,张龙. 水溶液中一步合成二吡咯甲烷类化合物[J]. 有机化学, 2012, 32(3): 616-620 |
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| 作者姓名： | 吴振豪 胡江磊 王凯凯 高超 王洪宇 张龙 |
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| 作者单位： | 长春工业大学吉林省石化资源与生物质综合利用工程实验室 长春130012 |
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| 摘 要： | 在水相中,以磷钨酸为催化剂,吡咯与羰基化合物为底物,室温下一步合成了二吡咯甲烷类化合物,反应产物纯度高,无需进一步纯化.该方法具有明显的环境友好、产率高和操作过程简便的优点.
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| 关 键 词： | 二吡咯甲烷 吡咯 羰基化合物 水 绿色化学 |
One-Step Synthesis of Dipyrromethanes in Water |
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| Wu, Zhenhao , Hu, Jianglei , Wang, Kaikai , Gao, Chao , Wang, Hongyu , Zhang, Long. One-Step Synthesis of Dipyrromethanes in Water[J]. Chinese Journal of Organic Chemistry, 2012, 32(3): 616-620 |
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| Authors: | Wu Zhenhao Hu Jianglei Wang Kaikai Gao Chao Wang Hongyu Zhang Long |
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| Affiliation: | Wu,Zhenhao Hu,Jianglei Wang,Kaikai Gao,Chao Wang,Hongyu Zhang,Long(Jilin Provincial Engineering Laboratory for the Complex Utilization of Petro Resources and Biomass,Changchun University of Technology,Changchun 130012) |
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| Abstract: | A novel and non-conventional synthesis of meso-substitued dipyrromethanes under the catalysis of H3PW12O40 in water at room temperature is described in this paper.The reactions were performed under mild conditions,affording various dipyrrometnanes in good to excellent yields and high purity. |
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| Keywords: | dipyrromethane pyrrole carbonyl compound water green chemistry |
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